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所属单位：材料科学与技术学院

发表刊物：SMALL METHODS

关键字：3D network architecture hierarchical porous carbon lithium-ion capacitors molybdenum disulfide polyimide nanosheets

摘要：Lithium-ion capacitors (LICs) are emerging as one of the most advanced energy storage devices by combining the virtues of both supercapacitor and lithium-ion battery. The key point of constructing high-performance LICs is to balance the electrochemical kinetics and capacity mismatch between battery-type anode and capacitive-type cathode materials. Herein, a strategy is presented for simultaneous manipulation of a MoS2/N-doped carbon microspheres anode and hierarchical porous carbon cathode by using polyimide precursor. Owing to the fast lithium diffusion rate, high pseudocapacitive behavior, and expanding the interlayer of the MoS2 composite network architecture, the material can achieve excellent rate capacity and cyclic stability. Hierarchical porous carbon has an ultrahigh specific surface area and superior capacitive behavior. A high-performance LIC is successfully constructed by using the superior anode and cathode materials. The device can deliver a maximum energy density of 120 Wh kg(-1) and keep the capacity retention of 85.5% after 4000 cycles, revealing the competition in advanced energy storage devices. Accordingly, the simultaneous manipulation of metal sulfide and hierarchical porous carbon by the same precursor can be used toward fabricating other ideal electrode structures for energy storage.

ISSN号：2366-9608

是否译文：否

发表时间：2019-07-10

合写作者：蒋江明,张亚迪,安玉峰,吴朗源,窦辉,张校刚

通讯作者：张校刚,朱清华