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所属单位：材料科学与技术学院

发表刊物：JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY

关键字：Shrinking hydrogel Pillar[5]arene Host-guest interaction Electrostatic effect

摘要：Polyacrylamide-based polymer networks were constructed as a hydrogel, and the novel and simple method was demonstrated to create dramatically shrinking hydrogels triggered by water-soluble pillar [5]arene (WP5)-based synergetic effect of host-guest recognition and electrostatic effect. The shrinking behavior of hydrogels was studied, which significantly exhibited an equilibrium shrinking percentage of approximately 89.2% in weight. More importantly, the WP5 controlled shrinking behavior of hydrogels was further investigated by the encapsulation and release of two types of small molecular drug models (anionic calcein and cationic rhodamine B), which displayed a much better selective release of anionic calcein than that of cationic rhodamine B, due to the host-guest interaction of WP5 and guest moiety of polymer networks in hydrogel as well as the electrostatic effect of anionic host molecule WP5. (C) 2017 Elsevier B.V. All rights reserved.

ISSN号：1010-6030

是否译文：否

发表时间：2018-03-15

合写作者：Wang, Sai,Xu, Zuqiang,Wang, Tingting,Liu, Xin,Lin, Yumo,Lin, Chen,Wang, Leyong

通讯作者：沈应中