余红发

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土木工程
交通运输工程
土木水利
交通运输

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Effects of sodium citrate and citric acid on the properties of magnesium oxysulfate cement

发布时间:2018-11-13 点击次数:

所属单位:航空学院

发表刊物:CONSTRUCTION AND BUILDING MATERIALS

关键字:Magnesium oxysulfate cement Sodium citrate Citric acid Mechanical strength Microstructure Water resistance

摘要:Magnesium oxysulfate (MOS) cement is a type of green inorganic cementitious material, with the advantages of light weight, low thermal conductivity, binding ability in light-weight panels, high temperature resistance and good fire resistance; however, its application range in practical engineering is limited by its low mechanical strength. In this paper, the influences of sodium citrate and citric acid as additives on the mechanical strength, water resistance, setting time, pH change, composition and microstructure of MOS cement were investigated. The sample properties were examined by means of mechanical strength test, Vicat apparatus, pH meter, X-ray diffraction (XRD), scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP). The results revealed that adding sodium citrate or citric acid could promote the large amount of 5 mg(OH)(2)-MgSO4.7H(2)O generation and improve the water resistance of MOS cement. The incorporation of sodium citrate or citric acid caused a reduction in the total porosity and the volume fraction of large pores (>100 nm) in MOS cement, as well as an increase in the most probable aperture and the volume fraction of small capillary pores (10 nm-100 nm). In addition, the setting time of MOS cement with sodium citrate or citric acid was longer than that without sodium citrate or citric acid. (C) 2018 Elsevier Ltd. All rights reserved.

ISSN号:0950-0618

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发表时间:2018-04-30

合写作者:Wang, Nan,Bi, Wanli,Tan, Yongshan,XT10370,Wu, Chengyou,麻海燕,Hua, Shi

第一作者:余红发

通讯作者:余红发

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