曲宁松

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教授 博士生导师

招生学科专业:
机械工程 -- 【招收博士、硕士研究生】 -- 机电学院
机械工程(微细制造及微机电系统) -- 【招收硕士研究生】 -- 机电学院
机械 -- 【招收博士、硕士研究生】 -- 机电学院

性别:男

毕业院校:南京航空航天大学

学历:南京航空航天大学

学位:工学博士学位

所在单位:机电学院

办公地点:明故宫校区

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An insight into cathodic reactions during wire electrochemical micromachining in aqueous hydrochloric acid solution

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所属单位:机电学院

发表刊物:Electrochim Acta

摘要:In wire electrochemical micromachining, insoluble products are still generated in spite of the use of acidic electrolyte and adhere onto the wire cathode. In this work, the compositions of the adhered products and their influences on the electrochemical characteristics of the wire cathode were studied. The XRD results suggest that the insoluble products are mainly composed of γ-Fe2O3 and α-FeOOH and that reduction of Fe ions occurs on the wire cathode to form metallic Fe (α-Fe). In addition, the electrochemical impedance spectroscopy measurement results indicate that the electrochemical characteristics of the wire cathode are significantly affected by the insoluble products. These insoluble products together with the deposited iron on the wire pose negative effects on the machining results. Finally, qualitative models for the cathodic reactions are proposed. © 2018 Elsevier Ltd

ISSN号:0013-4686

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发表时间:2019-01-01

合写作者:Gao, Chuanping,F70206553,沈一洲

通讯作者:曲宁松