姚正军

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教授 博士生导师

招生学科专业:
化学 -- 【招收硕士研究生】 -- 材料科学与技术学院
材料科学与工程 -- 【招收博士、硕士研究生】 -- 材料科学与技术学院
机械 -- 【招收博士、硕士研究生】 -- 材料科学与技术学院
材料与化工 -- 【招收博士、硕士研究生】 -- 材料科学与技术学院

主要任职:面向苛刻环境的材料制备与防护技术工业和信息化部重点实验室主任

其他任职:江苏省金属学会副理事长,江苏省热处理及表面改性工程技术研究中心副主任,江苏省机械工程学会材料工程专业委员会副理事长,江苏省复合材料学会常务理事

毕业院校:南京航空航天大学

学历:南京航空航天大学

学位:工学博士学位

所在单位:材料科学与技术学院

办公地点:江宁校区东区D10-材料楼A511

联系方式:13951818597

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The effect of polymerization temperature and reaction time on microwave absorption properties of Co-doped ZnNi ferrite/polyaniline composites

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所属单位:材料科学与技术学院

发表刊物:RSC Adv.

摘要:This study presents the systematic potential effects of reaction parameters on the synthesis of Co-doped ZnNi ferrite/polyaniline composites prepared via novel interfacial polymerization. Through intensive experiments and analysis, optimum reaction conditions including the polymerization temperature and reaction time are proposed so that the performance of the material is significantly improved. The structure, functional groups and morphologies of composites are investigated by X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), Fourier transform-infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM). In addition, the electromagnetic properties and microwave absorption properties of Co-doped ZnNi ferrite/polyaniline composites are examined by a vibrating sample magnetometer (VSM), Quantum Design (MPMS-VSM and MPMS-XL), the superconducting quantum interference device (SQUID) magnetometer and vector network analysis. Based on these analyses, it is found that by tuning the reaction conditions, i.e., polymerization temperature and reaction time, microwave absorption capabilities in terms of the maximum reflection loss (RL) value and absorber thickness can be readily optimized. The results show that the composite with an optimized polymerization condition of 20 &deg;C for 12 h displays remarkable microwave absorption properties with maximum reflectivity of -54.3 dB, and the effective bandwidth (RL < -10 dB) is about 6.02 GHz at a thickness of 6.8 mm. Furthermore, the discussion shows that the promising microwave absorption may be due to the uniform urchin-like structure of the composites. &copy; The Royal Society of Chemistry 2018.

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发表时间:2018-01-01

合写作者:Lei, Yiming,Lin, Haiyan,周金堂,Haidry, Azhar Ali,Liu, Peijiang

通讯作者:Lei, Yiming,姚正军