刘友文

教授 博士生导师

招生学科专业:
课程与教学论 -- 【招收硕士研究生】 -- 人文与社会科学学院
物理学 -- 【招收博士、硕士研究生】 -- 物理学院
电子信息 -- 【招收硕士研究生】 -- 物理学院

主要任职:江苏省物理学会,江苏省光学学会常务理事

其他任职:中国光学工程学会计算成像专委会委员

性别:男

毕业院校:中国科学院上海光学精密机械研究所

学历:中国人民共和国科学院上海光学精密机械研究所

学位:工学博士学位

所在单位:物理学院

办公地点:理学楼468

联系方式:13770938968,email:ywliu@nuaa.edu.cn,微信号:ycwhshnj

电子邮箱:

手机版

访问量:

最后更新时间:..

当前位置: 中文主页 >> 科学研究 >> 论文成果
Phase transition and near-zero thermal expansion properties of Zr0.5Hf0.5V2?xPxO7 (0???x???1.2)

点击次数:

所属单位:理学院

发表刊物:Solid State Commun

摘要:In the study, Zr0.5Hf0.5V2−xPxO7 (0 ≤ x ≤ 1.2) was prepared by solid state method and then the microstructure of synthesized samples was investigated. The microstructure, coefficient of thermal expansion (CTE) and phase transition of Zr0.5Hf0.5V2−xPxO7 (0 ≤ x ≤ 1.2) were investigated with thermal dilatometry, x-ray diffraction (XRD) and Raman spectroscopy. The results showed that the samples were single cubic phase with the space group of Pa3¯ in the crystal structure. When the substitution rate of P5+ was higher than 0.6, the 3 × 3 × 3 superstructure disappeared. The expansion coefficient of Zr0.5Hf0.5V1.2P0.8O7 was calculated to be −0.53 × 10−6 K−1 under the linear thermal expansion in a very wide temperature range from 300 to 573 K. With the increase of P5+ content, the temperatures of positive-to-negative thermal expansion of Zr0.5Hf0.5V2−xPxO7 firstly even decreased below room temperature and then increased. The synthesized Zr0.5Hf0.5V2−xPxO7 exhibited near zero thermal expansion behavior in a wide temperature range around room temperature. © 2018 Elsevier Ltd

ISSN号:0038-1098

是否译文:

发表时间:2019-01-01

合写作者:Wang, Junping,Chen, Qingdong,Li, Sailei,Ji, Yanjun,Zeng, GaoJie,Liang, Erjun

通讯作者:刘友文

版权所有©2018- 南京航空航天大学·信息化处(信息化技术中心)