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铁掺杂聚苯胺/功能化石墨烯制备高效Fe-N-C型氧还原催化剂研究
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Affiliation of Author(s):材料科学与技术学院

Journal:化工新型材料

Key Words:对苯二胺;功能化石墨烯;聚苯胺;氧还原反应;

Abstract:以对苯二胺(PPD)改性的氧化石墨烯(GO)为碳载体,三氯化铁(FeCl 3 )为金属源,聚苯胺(PANI)为氮源,经高温热处理和酸蚀制备了结构均匀的铁-聚苯胺/功能化石墨烯(Fe-PANI/PGO)催化剂,并考察其对氧气(O 2 )的催化还原性能。结果表明:Fe-PANI/PGO催化还原的起始电位和半波电位可分别达到-0.057V和-0.122V,极限电流密度更是达到了-5.145mA/cm 2 。同时,阐明了Fe-PANI/PGO催化剂的催化活性提升主要归因于碳结构无序性的增大。

Translation or Not:no

Date of Publication:2018-09-15

Co-author:,赵媛,赵清清,陈志雄

Correspondence Author:xjj

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Professor

Gender:Male

Alma Mater:南京林业大学

Education Level:With Certificate of Graduation for Doctorate Study

Degree:Doctoral Degree in Engineering

School/Department:College of Material Science and Technology

Discipline:Material Process Engineering. Physical Chemistry

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