Affiliation of Author(s):材料科学与技术学院

Journal:APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING

Key Words:INFRARED QUANTUM COUNTERS NANOPARTICLES LUMINESCENCE NANOCRYSTALLINE DEPENDENCE Y2O3-ER3+ EMISSION YIELD

Abstract:NaY(WO4)(2): Er3+ phosphors with various doping concentrations of [Er3+]/([Er3+]+[Y3+]) (0, 5, 7, 10, 12, 15%) were successfully synthesized by high-temperature solid-state reaction. X-ray diffraction (XRD) measurement demonstrated the presence of tetragonal-phase NaY(WO4)(2) phosphors and Fourier transform infrared (FT-IR) spectra showed a strong upsilon(3) stretching vibration mode of WO4 (2-), indicating the good crystallization of the phosphors. Well-crystallized phosphors showed a fine morphology with particle sizes of 0.8-10 A mu m by scanning electron microscope (SEM). Under excitation of 980 nm laser, Er3+-doped phosphors exhibited strong green emissions centered at 527 and 549 nm in addition to a 665 nm emission band in the red region, which were assigned to the H-2(11/2), S-4(3/2) -> I-4(15/2) and F-4(9/2) -> I-4(15/2) transitions, respectively. When the doping concentration was 10%, the intensities of green and red emissions reached their maximum values, stronger than that in 5% Er3+ doped one by 13 times. The double-logarithm plot of the upconversion (UC) emission intensity to the excitation power for different Er3+ doping concentrations depicted that at least two infrared photons were involved for every emitted green and red photon. UC emission intensity changing with temperature displayed different trends for the phosphors with different Er3+ concentrations. The enhancement for green emission band centered on 549 nm could reach 50 times at 30 K in sample with 5% Er3+ concentration. Under excitation by 355 nm laser, all the phosphors showed a strong PL emission band at 430 nm, while green luminescence band locating from 540 to 570 nm was only observed in 7, 10, and 12% Er3+-doped phosphors, which was ascribed to S-4(3/2) -> I-4(15/2) transition.

ISSN No.:0947-8396

Translation or Not:no

Date of Publication:2018-07-01

Co-author:杨楠楠,翟子豪,Lily

Correspondence Author:shl