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Synthesis of a novel tripod BODIPY dye bearing N-hydroxysuccinimide ester and its amidation

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Affiliation of Author(s):材料科学与技术学院

Title of Paper:Synthesis of a novel tripod BODIPY dye bearing N-hydroxysuccinimide ester and its amidation

Journal:SYNTHETIC COMMUNICATIONS

Key Words:Amidation boron dipyrromethene (BODIPY) hydrogenolysis N-hydroxysuccinimide ester tripod

Abstract:A novel tripod boron dipyrromethene (BODIPY) dye bearing N-hydroxysuccinimide ester was synthesized through its carboxylic acid precursor, and the functionality was confirmed by its amidation reaction with a primary amine. It is the first time that a reactive functional group was introduced onto a tripod BODIPY structure. All the new structures had been characterized by NMR, HRMS, and IR spectra. The introduction of an electron-donative diethylamine proved to be a key factor for the successful hydrogenolysis of the corresponding tris-substituted 1,3,5-triazine structure. [GRAPHICS] .

ISSN No.:0039-7911

Translation or Not:no

Date of Publication:2018-01-01

Co-author:qx,Nie, Kaiqiang

Correspondence Author:沈霖

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