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个人信息Personal Information
教授 博士生导师
招生学科专业:
化学 -- 【招收硕士研究生】 -- 材料科学与技术学院
材料科学与工程 -- 【招收博士、硕士研究生】 -- 材料科学与技术学院
材料与化工 -- 【招收博士、硕士研究生】 -- 材料科学与技术学院
能源动力 -- 【招收博士、硕士研究生】 -- 材料科学与技术学院
性别:男
学历:南京大学
学位:理学博士学位
所在单位:材料科学与技术学院
办公地点:江宁校区1号楼14楼408A
联系方式:18005152399
电子邮箱:
Composition Design and Structural Characterization of MOF-Derived Composites with Controllable Electromagnetic Properties
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所属单位:材料科学与技术学院
发表刊物:ACS SUSTAINABLE CHEMISTRY & ENGINEERING
关键字:MOF-derived composites Metallic carbides Composition design Tunable electromagnetic properties Microwave absorption
摘要:Simply and effectively achieving the tunability of the composition and chemical state of each component remains a challenge for modifying the electromagnetic performance of metal-organic-framework-derived (MOF-derived) composites. In this work, quaternary ZnO/Fe/Fe3C/carbon composites have been successfully synthesized by thermal decomposition of Fe-III-MOF-5. The composition and chemical state of each component can be effectively controlled by changing the heating temperature. In detail, with increasing temperature, the Fe element would be transformed from Fe3+ to Fe3C and Fe, which also leads to the graphitization and weight loss of carbon. The effects on electromagnetic properties are also investigated, and the ZFC-700 sample possesses optimized reflection loss (RL) performance with an RL value of 30.4 dB and a broad effective frequency bandwidth of 4.96 GHz at a thin thickness of only 1.5 mm. Conduction loss, interfacial polarization, ferromagnetic resonance, and interference cancelation should be responsible for ideal electromagnetic absorption. The porous quaternary composites not only convert incident electromagnetic energy to heat rather than reflect it back which is in favor of solving electromagnetic pollution, but also reduce the consumption of the metal source and poisonous raw materials for traditional microwave-absorbing materials.
ISSN号:2168-0485
是否译文:否
发表时间:2017-09-01
合写作者:刘伟,刘伟,刘磊,李道冉,张亚男,马建娜,都有为
通讯作者:姬广斌