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南京大学

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Achieving better impedance matching by a sulfurization method through converting Ni into NiS/Ni3S4 composites

Date of Publication:2018-02-21 Hits:

Affiliation of Author(s):材料科学与技术学院
Journal:JOURNAL OF MATERIALS CHEMISTRY C
Key Words:MICROWAVE-ABSORPTION PROPERTIES ELECTROMAGNETIC-WAVE ABSORPTION METAL-ORGANIC-FRAMEWORKS SENSITIZED SOLAR-CELLS IN-SITU SYNTHESIS FACILE SYNTHESIS EVOLUTION REACTION NICKEL SULFIDE PERFORMANCE GRAPHENE
Abstract:Herein, we synthesized metallic Ni through a simple chemical reduction process. Unfortunately, the Ni showed poor microwave absorption performance because of the inferior impedance matching properties. To overcome this, a sulfurization method was employed to obtain a novel microwave absorber-NiS/Ni3S4 composite. The nickel sulfide composites displayed much better microwave absorption abilities than the metallic Ni. The reflection loss (RL) values that exceeded -10 dB were observed in the frequency range 13.8-18.0 GHz (a broad microwave absorption bandwidth of 4.2 GHz) with a thickness of only 1.8 mm. Besides, the minimum RL value was as high as -43.0 dB at 9.1 GHz with the thickness of 2.4 mm. On the basis of high dielectric loss, good impedance matching properties, as well as stronger interfacial polarization effect, it can be concluded that NiS/Ni3S4 composites possess strong-absorption properties and have great potential for application as light microwave absorbers.
ISSN No.:2050-7526
Translation or Not:no
Date of Publication:2018-02-21
Co-author:吕婧,成岩,刘伟,lw,权斌,梁小会,都有为
Correspondence Author:jiguangbin