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实验师 硕士生导师
招生学科专业:
化学 -- 【招收硕士研究生】 -- 材料科学与技术学院
材料科学与工程 -- 【招收硕士研究生】 -- 材料科学与技术学院
材料与化工 -- 【招收硕士研究生】 -- 材料科学与技术学院
性别:男
毕业院校:南京航空航天大学
学历:南京航空航天大学
学位:工学博士学位
所在单位:材料科学与技术学院
联系方式:chentian@nuaa.edu.cn
电子邮箱:
Enhanced dielectric performance of poly(vinylidene fluoride) composite filled with copper phthalocyanine-titanium dioxide ball milling hybrids
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所属单位:材料科学与技术学院
发表刊物:MATERIALS LETTERS
关键字:Poly(vinylidene fluoride) Copper phthalocyanine Titanium dioxide Polymeric composites Electrical properties
摘要:The hybrid of organic semiconductor copper phthalocyanine (CuPc) and inorganic semiconductor titanium dioxide (TiO2) was synthesized by a simple ball milling processing. Structural properties of CuPc-TiO2 composites were characterized by X-ray diffraction (XRD), and transmission electron microscopy (TEM). The CuPc-TiO2 hybrid was used as nanofiller within flexible dielectric poly(vinylidene fluoride) (PVDF) matrix. The dispersion of fillers was characterized by cross-section scanning electron microscope (SEM). The conjugated structure of CuPc nanosheets in CuPc-TiO2 hybrid could provide huge p-associated orbital for electron delocalization and thus enhanced the dielectric constant of the corresponding PVDF composites. The dielectric constant of PVDF composite filled with 20%(CuPc-TiO2) ball-milling hybrid was 114.71 at 1 Hz, which was almost 7.8 times higher than the dielectric constant of 20% TiO2-PVDF composite and 20 times higher than that of the pure PVDF. (C) 2017 Elsevier B.V. All rights reserved.
ISSN号:0167-577X
是否译文:否
发表时间:2017-12-15
合写作者:Liu, Bo
通讯作者:陈田